Tetraamminepalladium(II) dichloride ammonia tetrasolvate
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چکیده
The title compound, [Pd(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt Pd(en)Cl2 (en is ethylenediamine) and is isotypic with [Pt(NH3)4]Cl2·4NH3 [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol-ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol-ecules. These are either bound in the palladium complex or solvent mol-ecules. The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H⋯N and N-H⋯Cl inter-actions with nearly ideal hydrogen-bonding geometry.
منابع مشابه
Tetraammineplatinum(II) dichloride ammonia tetrasolvate
The title compound, [Pt(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt PtCl2. The platinum cation is coordinated by four ammonia mol-ecules, forming a square-planar complex. The chloride anions are surrounded by nine ammonia mol-ecules, either bound within the platinum complex or solvent mol-ecules. The solvent ammonia mol-ecules are packed in such a way that an extended netwo...
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